Enhancing the water permeability of composite NF membranes through the incorporation of organic ions in the aqueous phase

Composite nanofiltration (NF) membranes prepared using interfacial polymerization (IP) have gained significant attention in the field of wastewater treatment. In this study, sodium camphor sulfonate (CSA-Na) and tetraethylammonium chloride (TEAC) were employed as aqueous phase additives to regulate the diffusion of piperazine (PIP) molecules through electrostatic interactions. The dissociated CSA-Na and TEAC in the aqueous solution formed an organic structure at a certain concentration, restricting the interfacial transport behavior of PIP monomers. The results show that when the content of CSA-Na is 2% w/v, TEAC is 3.9% w/v, that is, the material dosage ratio is 1 : 3, and the NF membrane shows the best performance, with a water flux of 55.61 L m−2 h−1 (test pressure is 0.5 MPa), and MgSO4 rejection rate of more than 98%.