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Electromagnetic porous lignocellulosic matrix composites: A green electromagnetic shielding material with high absorption efficient electromagnetic interference

INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES [2024]
Wenyao Feng, Qinglei Xu, Jiahao Zhao, Wei Zhang, Yuanyuan Yu, Guangfu Qian, Minsheng Lu, Lianhua Fu, Changzhou Chen, Douyong Min
ABSTRACT

Electromagnetic interference (EMI) shielding materials play a vital role in human society, especially in light of the rapid development of electronic communication equipment. Therefore, it is urgent to develop green, high-efficiency EMI shielding materials. Wood, as a renewable raw material, possesses significant structural advantages in studying EMI materials due to its unique 3D pore structure . Herein, we report magnetoelectric lignocellulosic matrix composites derived from the delignified wood for efficient EMI shielding. The composite was fabricated by in-situ polymerization of PEDOT conductive coating and magnetic Fe 3 O 4 in delignified wood. The conductive 3D pore structure of Fe 3 O 4 /PEDOT@wood could effectively cause dielectric loss and multiple internal reflections. Combined with the magnetic loss of Fe 3 O 4 , the material exhibited excellent EMI shielding effectiveness (SE), which could be attributed to the synergistic effect of dielectric and magnetic losses. The Fe 3 O 4 /PEDOT@wood showed excellent conductivity (103 S/m), good magnetism (26.7 emu/g), the EMI SE up to 59.8 dB, and high SE A /SE T ratios of∼84.2 % to 95.7 % at 2 mm in X -band. Moreover, the material exhibited a high compressive strength and tensile strength of 100.8 MPa and 18.1 MPa, respectively. Therefore, this work provided a reference for the preparation of high-efficiency EMI shielding materials.

MATERIALS

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