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Effect of interface roughness on the CMAS + molten salt (Na2SO4 + NaCl + NaVO3) corrosion resistance of EB-PVD thermal barrier coatings

SURFACE & COATINGS TECHNOLOGY [2025]
Xiaopeng Hu, Sai Liu, Qing Liu, Yang Su, Junyao Wu, Zhihang Xie, Jinwei Guo, Wang Zhu
ABSTRACT

The service life of thermal barrier coatings (TBCs) in calcium magnesium aluminosilicate (CMAS) and molten salt environments has become a key factor in determining engine reliability and safety. The effect of interface roughness (bond coating surface roughness) on the CM (CMAS + molten salt (Na 2 SO 4  + NaCl + NaVO 3 )) corrosion resistance of electron beam physical vapor deposition (EB-PVD) TBCs is investigated. The addition of molten salts lowers the melting point of CM, leading to more severe destructive effects compared to single CMAS corrosion. Moreover, the 1200# specimen (Ra = 2.0 μm) exhibits the best resistance to CM corrosion. The adjustment of interface roughness significantly alters the microstructure of the top-ceramic coating and induces changes in crack patterns after CM corrosion. Therefore, appropriately reducing interface roughness is key to improving the isothermal CM corrosion resistance and high-temperature CM corrosion-induced thermal shock performance of TBCs.

MATERIALS

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