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Dye adsorption and antimicrobial performances of composite nanofiber membranes containing cuprammonium cellulose

SEPARATION AND PURIFICATION TECHNOLOGY [2024]
Danish Iqbal, Raza Ullah, Renhai Zhao, Yuejie Dou, Di Yan, Xin Ning
ABSTRACT

This research presents a novel and efficient process for Congo Ced (CR) dye removal together with exceptional antimicrobial performance using a dual-functional composite membrane. The membrane fabrication involves the electro-spun infusion of cuprammonium cellulose solution with polyethylene oxide (PEO) and polyacrylonitrile (PAN) in a conjugated fashion. The composite membrane exhibits 94.0 % dye removal capability and 41 mg/g adsorption capacity. The adsorption kinetics was proved to conform to the pseudo-second-order (PSO) model, and the equilibrium adsorption results were accurately defined by the Dubinin-Radushkevich model, indicating the process of adsorption as a physical, exothermic interaction that occurs spontaneously. The dye removal efficacy of the membrane in the first and fifth usage was 94.5 and 84.2 %, respectively, demonstrating its effectiveness, stability, and reusability. The composite membrane also exhibited effective antibacterial performance regarding Staphylococcus Aureus and Escherichia Coli ( S. aureus & E. coli ) with 99 % bacterial reduction capability at high permeation flux of ∼13,000 L m −2 h −1 . Hence, the fibrous composite materials demonstrated its potential to be an ideal choice for water treatment in textile mills, especially in developing countries.

MATERIALS

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