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Double perovskite quantum dots Cs2AgInCl6: Tb3+/Sm3+/Bi3+ for dual-mode fluorescence temperature sensing

MATERIALS RESEARCH BULLETIN [2024]
Chenglin Gong, Lin Lin, Yingzhen Wu, Yanan Zhang, Zhuohong Feng, Zhezhe Wang, Yantang Huang, Zhiqiang Zheng
ABSTRACT

In this research, double perovskite quantum dots Cs 2 AgInCl 6 : Tb 3+ /Sm 3+ /Bi 3+ are synthesized employing a high-temperature thermal injection method. The temperature-dependent emission spectra and the fluorescence decay curves of samples show the quantum dots can be applied to dual-mode temperature sensing employing fluorescence intensity ratio technique (between 656 nm (Sm 3+ ) and 549 nm (Tb 3+ )) and fluorescence lifetime thermometry (549 nm (Tb 3+ )), achieving maximal relative sensitivities of 3.24%/K (351 K) and 0.68%/K (373 K), respectively. This study offers valuable insights into the temperature sensing capabilities of these quantum dots, which shows that these quantum dots are promising high-sensitivity dual-mode temperature sensing materials.

MATERIALS

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