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A novel Yb2SiO5 ceramic aerogel with excellent thermal stability for high-temperature thermal insulation

CERAMICS INTERNATIONAL [2024]
Sisi Shang, Jie Wang, Zihan Wang, Zihao Song, Man Yuan, Qi You, Longhui Ge, Jian Yang, Sheng Cui
ABSTRACT

To investigate the potential of rare earth oxide structural ceramics for high-temperature insulation applications, we introduced aerogel structures into Yb 2 SiO 5 ceramics. In this study, the pure Yb 2 SiO 5 ceramic aerogels were successfully prepared by calcination using formamide as a gelling agent, the sol-gel method, and the CO 2 supercritical drying method. The results indicate that the Yb 2 SiO 5 ceramic aerogel exhibits exceptional structural and phase stability at a temperature of 1400 °C. In addition, we have developed Yb 2 SiO 5 ceramic aerogel composites reinforced with aluminosilicate fiber cotton, which exhibit low density (228.77 kg m −3 ) and low thermal conductivity (0.038 W m −1  K −1 at 25 °C, 0.102 W m −1  K −1 at 1000 °C). The back temperature of the 10 mm thick composites is only 285 °C after exposure to a butane blowtorch flame at 1300 °C for 600 s. This demonstrates its excellent high-temperature insulation performance. This work can provide a basis for further design and preparation of oxide ceramic high-temperature thermal protection materials with controllable morphology and properties.

MATERIALS

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