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Low temperature calcination induced flexibility in purely inorganic lead zirconate titanate and its application in piezoelectric enhanced adsorption

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY [2021]
Longlong Jiang, Xiao-Xiong Wang, Jun Zhang, Hao Hong, Kefan Du, Yifei Zhang, Yanqiang Li, Yongcheng Zhang, Yunze Long, Keqing Ruan
ABSTRACT

It is a challenge to achieve flexibility in purely inorganic piezoelectric materials without organic support, and various thin film flexible inorganic piezoelectric materials has been developed recently. In this work, lead zirconate titanate (PZT) nanofiber membranes were prepared by electrospinning, and a flexible membranes can be obtained by reducing the calcination temperature, and the flexibility was characterized by the three-point method. The fiber membrane was relatively thicker in relative to thin films and confirmed to adsorb Congo Red quickly under the action of ultrasound. The maximum adsorption capacity is 61.78 mg g −1 and saturation time reaches 20 min under ultrasound treatment. In addition, the color change after saturation adsorption can quickly determine the actual load of the fiber membrane. In the future, this load saturation effect can be used to calibrate the relationship between the piezoelectric signal and the adsorption load, so as to obtain more accurate chemical sensors.

MATERIALS

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