Sustainable and effective degradation of aniline by sodium percarbonate activated with UV in aqueous solution: Kinetics, mechanism and identification of reactive species

In recent decades, sodium percarbonate (SPC) has been widely applied as a solid replacement for H 2 O 2 in advanced oxidation process (AOPs). In this study, ultraviolet (UV) light was utilized for SPC activation to investigate the aniline degradation performance. The effects of SPC dosages and UV irradiation on aniline degradation were elaborated. The removal efficiency was significantly improved by increasing either the SPC dosage or UV irradiation intensity. Moreover, scavenging experiments showed that •OH, CO 3 •− , and O 2 •− were the predominant reactive species for aniline degradation. Meanwhile, the variation in the amount of •OH in the UV/SPC system was monitored, which revealed the dominant role of •OH. As a result, the mechanism of aniline degradation by the UV/SPC system was demonstrated based on confirmed free radicals. Furthermore, aniline degradation by the UV/H 2 O 2 and UV/H 2 O 2 /Na 2 CO 3 system were compared with the UV/SPC system, and an enhancement by the addition of Fe(II) in the UV/SPC system was verified. Aniline degradation was not significantly affected by the initial pH or the presence of Cl − , SO 4 2− while NO 3 − , HCO 3 − and humid acid (HA) suppressed the reaction. In general, the UV/SPC system is a novel, green, and promising technology for aniline removal from aqueous solutions.