Selective Ligand Sensitization of Lanthanide Nanoparticles for Multilevel Information Encryption with Excellent Durability

Durable and multilevel information encryption technology has been of great importance in recent decades. Here, an inkjet printer-adaptable invisible ink was prepared with lanthanide nanoparticles, and optical decoding of information could only be achieved when specific ligand dipicolinic acid was utilized in the presence of UV illumination. In addition, the proposed protocols displayed long shelf life (>one year) and excellent durability even at harsh conditions such as in the presence of strong acids (1 M HCl) and alkalis (1 M NaOH). Meanwhile, such invisible inks could be further employed on a soft matrix via screen-printing, holding great potential for practical applications.