Fabrication of actiniae-like atomically thin hydroxylation boron nitride@polyaniline hierarchical composites with adjustable high thermal conductivity and electrical conductivity

Polyaniline (PANI) has been studied as soft electronic materials, which is still subject to performance obstacles such as low thermal conductivity and undesirable electrical conductivity. Herein, we report the in situ preparation of an atomically thin hydroxylated boron nitride (HO-BNNS)@PANI actiniae-like layered composite. HO-BNNS@PANI composite obtains brilliant electrical and thermal conductivity without destroying the pH sensitivity of PANI. In this case, the test results show that when the HO-BNNS content is 15 wt%, the conductivity of the HO-BNNS@PANI composite is 10.8 S cm−1, and the thermal conductivity is 1.21 W m−1·K−1 (≈520% that of pure PANI). More strikingly, the HO-BNNS@PANI composite maintains the pH responsiveness of the intrinsic PANI. This greatly improves the application range of composite materials. Meanwhile, since actiniae-like structural factors simultaneously improve ion diffusion capability and optimize reaction area, after five times of doping and dedoping, the conductivity of the HO-BNNS@PANI composite can still be maintained above 60%.