Effects of anionic hydrocarbon surfactant on the transport of perfluorooctanoic acid (PFOA) in natural soils

The widespread usage of per- and polyfluoroalkyl substances (PFASs) has led to their ubiquitous co-existence with hydrocarbon surfactants in the subsurface environment. In this study, column experiments were conducted to investigate the effect of an anionic hydrocarbon surfactant (sodium dodecylbenzene sulfonate, SDBS, 1 and 10 mg/L) on the transport of perfluorooctanoic acid (PFOA) in two saturated natural soils under different cation type (Na + and Ca 2+ ) conditions. Results showed that SDBS (10 mg/L) significantly enhanced the transport of PFOA in two soils. This was likely because SDBS had a stronger adsorption affinity to the soils than PFOA, and can outcompete PFOA for the finite adsorption sites on the soil surface. The effect of SDBS on PFOA transport varied greatly in the two soils. More negatively charged soil surface and greater soil particle size likely contributed to the more noticeable transport-enhancement of PFOA resulting from the presence of SDBS. Also, the enhancement effect of SDBS (10 mg/L) with Ca 2+ on PFOA transport was more significantly than that with Na + . This was possibly due to the blocking effect of SDBS to the more positively charged soil surface induced by Ca 2+ . Findings of this study point out the importance of anionic hydrocarbon surfactants on PFOA transport when assessing its environmental risks and implementing remediation efforts.