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Promoted interfacial charge transfer by coral-like nickel diselenide for enhanced photocatalytic hydrogen evolution over carbon nitride nanosheet

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY [2022]
Xue Zhang, Chuanjun Xi, Yuanhang Yue, Puhui Deng, Linping Zhang, Yu Hou
ABSTRACT

Seeking an efficient and non-precious co-catalyst for g-C 3 N 4 (CN) remains a great demanding to achieve high photocatalytic hydrogen generation performance. Herein, a composite photocatalyst with high efficiency was prepared by modifying CN with coral-like NiSe 2 . The optimal hydrogen evolution rate of 643.16 μmol g −1  h −1 is from NiSe 2 /CN-5 under visible light. Superior light absorption and interfacial charge transfer properties including suppressed photogenerated carrier recombination and efficient separation of photogenerated electron-hole pairs have been observed, which account for the enhanced photocatalytic performance of CN.

MATERIALS

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