Facile synthesis and evaluation of three magnetic 1,3,5-triformylphloroglucinol based covalent organic polymers as adsorbents for high efficient extraction of phthalate esters from plastic packaged foods

Three covalent organic polymers (COPs) were successfully fabricated by room-temperature solvent-free mechanochemical grinding method between 1,3,5-triformylphloroglucinol (TP) and p -phenyl enediamine (COP1), benzidine (COP2), 4, 4″-diamino-p-terphenyl (COP3), and followed by coprecipitation on the surface of Fe 3 O 4 nanoparticles to form three corresponding magnetic Tp-series COPs. The fabricated magnetic COPs were evaluated and then applied for the extraction of phthalate esters from food samples before gas chromatography-tandem spectrometry analysis. Magnetic COP2 exhibited the highest extraction efficiency, which can be attributed to its larger pore size, and its strong hydrophobic and π-π interactions with phthalate esters. The method possessed good linearity (10–1000 μg·kg −1 ), high sensitivity (0.29–2.59 µg·kg −1 for LODs and 0.97–8.63 µg·kg −1 for LOQs), and satisfactory recoveries (70.2–108.1%) with relative standard deviations lower than 5.2%. This method has potentials for high efficient separation/preconcentration of hydrophobic phthalate esters from foods.