TiN/Fe2Ni2N/SiO2 composites for magnetic-dielectric balance to facilitate temperature-stable broadband microwave absorption

Dielectric ceramics composites are potential high-temperature microwave absorption materials (MAMs), and the critical challenge is to achieve high-efficiency and temperature insensitive absorption characteristics suitable for wide temperature and frequency range. Herein, the electromagnetic attenuation properties of TiN/Fe 2 Ni 2 N/SiO 2 composites are studied in detail. The magnetic ceramic composites proposed exhibited stable attenuation behaviors at a wide temperature range (293–873 K). Notably, the optimal reflection loss (RL) value had reached −32.4 dB with a thickness of 2.8 mm at 373 K, and the effective absorption bandwidth (EAB) covered 3.89 GHz at 873 K. The excellent high-temperature attenuation capacity is attributed to the balancing strategy of dielectric and magnetic losses, as well as multiple polarization loss behaviors. The results showed that introducing magnetic components to form magnetic ceramic composites might shed light on the development of the TiN ceramic family for promising MAMs at a wide temperature range.