Superhydrophobic polyphenylene sulfide fiber paper with nanofiber network-like structure prepared via regulation of TIPS process for oil/water separation

The interface structure greatly affects the material surface wettability. Polyphenylene sulfide (PPS) fiber paper was modified via regulation of thermally induced phase separation process to obtain interfacial nanofiber network-like morphology, which obeyed nucleate-growth mechanism with the PPS resin on the fiber surface as the core. PPS nanofiber network layer with rough concave surface feature endowed the modified PPS fiber paper with stable superhydrophobic properties, and it showed excellent oil absorption and oil/water separation performance. The separation efficiency of using P -2 paper to separate the five oil/water mixtures listed in this paper were more than 99.99%, and the kerosene flux was more than 7350 L m −2  h −1 driven by gravity. Excellent hydrophobicity and cycling performance made PPS fiber paper with excellent reusability. In addition, the PPS fiber paper had also been proved to be used in strong acid–base and organic solvents for a long time. This work provided a PPS fiber paper for oil/water separation with simple preparation process, which was expected to be produced in large scale and applied in industrial field. Graphical abstract