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Microstructure and electromagnetic properties of low-temperature sintered NiCuZn ferrite by co-doped Bi2O3 and Co2O3

JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS [2023]
Shen Chang, Zhao Ye, Ji Xinran, Dong Shijun, Zheng Hui, Hu Ji, Zheng Liang
ABSTRACT

In this work, the electromagnetic of NiCuZn ferrite was enhanced and the sintering temperature was decreased by co-doped Bi 2 O 3 and Co 2 O 3 . The influence of the doping concentration of Co 2 O 3 on the microstructure and magnetic properties of NiCuZn ferrite was studied. Characterizations display that the high density and uniform microstructure of NiCuZn ferrite was obtained at a low sintering temperature of 925 °C. The Co ions were doped in the octahedral B-sites and decreased lattice constant and grain size. The resistivity was also improved after doping appropriate Co ions for the decrease of the Fe 2+ . The saturation magnetization, coercivity, permeability, and cut-off frequency were also enhanced after being doped with the Co 2 O 3 . Consequently, the NiCuZn ferrite doped with 0.30 wt% Bi 2 O 3 and 0.4 wt% Co 2 O 3 possesses a saturation magnetization of ~ 60.014 emu/g, coercivity of ~ 0.033 kA/m, real part of permeability of ~ 269.9 @ 1 MHz, and high cut-off frequency of 8.08 MHz, which can be applied in multi-layer chip inductors.

MATERIALS

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