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2D/2D BiOIO3/Ti3C2 MXene nanocomposite with efficient charge separation for degradation of multiple pollutants

APPLIED SURFACE SCIENCE [2023]
Bing Liu, Xia Zhang, Jialong Chu, Fei Li, Caixia Jin, Jing Fan
ABSTRACT

Co-catalysts can achieve efficient separation of photogenerated carriers and are considered as a promising strategy for solar photocatalytic removal of pollutants. Herein, we reported the synthesis of nanocomposite of BiOIO 3 /Ti 3 C 2 MXene combining two dimensional 2D BiOIO 3 with 2D Ti 3 C 2 MXene co-catalyst. The few-layered 2D Ti 3 C 2 MXene provided more adsorption and reaction sites. Furthermore, the synergism of intimate interfacial contact between the two 2D nanosheets and robust metallic electrical conductivity of Ti 3 C 2 MXene significantly accelerated the separation and migration of photogenerated charge carriers. A variety of organic pollutants were proved to be effectively degraded by 2D/2D BiOIO 3 /Ti 3 C 2 MXene composites. The degradation efficiencies followed the order tetracycline hydrochloride (93.4 %) > diclofenac sodium (87.6 %) > levofloxacin hydrochloride (77.4 %) > 4-nitrophenol (43.3%). Besides, the satisfactory recycling and stability of BiOIO 3 /Ti 3 C 2 MXene for the degradation of organic pollutants in water under solar irradiation predicted its good prospect for practical applications.

MATERIALS

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