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Eco-friendly wood plastic composites with biomass-activated carbon-based form-stable phase change material for building energy conversion

INDUSTRIAL CROPS AND PRODUCTS [2023]
Jianuo Xu, Jingmeng Sun, Junqi Zhao, Weiye Zhang, Jun Zhou, Liang Xu, Hongwu Guo, Yi Liu, Daihui Zhang
ABSTRACT

Phase change materials (PCM) can store heat energy through the process of phase change and keep the ambient temperature in a comfortable range, thus reaching the aim of energy conservation and emission reduction. To improve the latent heat capacity, activated carbon (AC) with a dendritic pore structure was used as the carrier, and polyethylene glycol (PEG) was loaded by vacuum adsorption method. A dendritic pore structure with a nesting pattern of macropores , mesopores, and micropores was formed through the steam activation process of waste wood chips , leading to a high load capacity (70%) and uniform distribution, which showed high heat storage performance (ΔH m reached 116 J/g). Then the form-stable phase change material with satisfactory performance (AC/PEG-70) was combined with wood flour/ high-density polyethylene (WF/HDPE) through blending and hot pressing to fabricate phase change heat storage wood-plastic composite material (A-WPC). When the AC/PEG-70 content was 50%, the elongation at break increased by 167% (20%), and the rigidity of the material enhanced. ΔH m of A-WPC-50 was 19 J/g, undoubtedly at this point, achieving the expected thermal performance. Thus, we prepared an eco-friendly wood-plastic composite with high latent heat capacity and high stability by using the dendritic pore structure of biomass activated carbon-based form-stable PCM, which has great significance in promoting energy conservation and emission reduction, responding to green technological innovation and promoting the development of the green and low-carbon industry.

MATERIALS

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