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Lignin/sodium alginate hydrogel for efficient removal of methylene blue

INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES [2023]
Chao Wang, Xuezhen Feng, Shibin Shang, He Liu, Zhanqian Song, Haibo Zhang
ABSTRACT

In this work, a class of bio-based hydrogels (LN-NH-SA hydrogel) were prepared from aminated lignin and sodium alginate. The physical and chemical properties of the LN-NH-SA hydrogel were fully characterized using field emission scanning electron microscopy , thermogravimetric analysis , fourier transform infrared spectroscopy , N 2 adsorption–desorption isotherms, and other techniques. LN-NH-SA hydrogels were tested for the adsorption of dyes (methyl orange and methylene blue). The LN-NH-SA@3 hydrogel showed better adsorption efficiency for MB with a maximum adsorption capacity of 388.81 mg·g −1 , a bio-based adsorbent with a high adsorption capacity. The adsorption process followed the pseudo-second-order model and fitted to the Freundlich isotherm equation. More importantly, LN-NH-SA@3 hydrogel maintained 87.64 % adsorption efficiency after 5 cycles. Overall, the proposed hydrogel with environmentally friendly and low cost is promising for the absorption of dye contamination.

MATERIALS

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