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Isobaric Vapor–Liquid Equilibrium for Binary System of 2-Methylpyridine + 2-Vinylpyridine at (1.9, 4.0 and 5.3) kPa

JOURNAL OF SOLUTION CHEMISTRY [2023]
Guo Qiang, Lin Jinyuan, Yang Pengju, Jiang Yong, Zhang Binchuan, Zhu Longxin, Wang Xunqiu
ABSTRACT

Isobaric vapor–liquid equilibrium (VLE) data for 2-methylpyridine + 2-vinylpyridine binary systems have been measured using a dynamic circulation device with the pressure points 1.9 kPa, 4.0 kPa, and 5.3 kPa at temperature in the range from 302.8 to 348.5 K. The VLE data passed the thermodynamic consistency test by using L–W method, R–K method and Fredenslund method. The NRTL, Wilson and UNIQUAC models were used to fit the data and binary interaction parameters were obtained for the three models. For these models, the results showed that the calculated values of the model were in good agreement with the experimental values and could, thereby, be used for the design and optimization of distillation.

MATERIALS

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