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PtNi-W/C with Atomically Dispersed Tungsten Sites Toward Boosted ORR in Proton Exchange Membrane Fuel Cell Devices

Nano-Micro Letters [2023]
Wang Huawei, Gao Jialong, Chen Changli, Zhao Wei, Zhang Zihou, Li Dong, Chen Ying, Wang Chenyue, Zhu Cheng, Ke Xiaoxing, Pei Jiajing, Dong Juncai, Chen Qi, Jin Haibo, Chai Maorong, Li Yujing
ABSTRACT

A hybrid electrocatalyst consisting of PtNi-W alloy nanocrystals loaded on carbon surface with atomically dispersed W sites was realized. Single-atomic W formed protonic acid sites and established an extended proton transport network at the catalyst surface. Peak power density is enhanced by 64.4% compared to that with the commercial Pt/C catalyst in fuel cell as cathode at ultra-low loading of 0.05 mg Pt cm −2 .

MATERIALS

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