CoFe2O4/WS2 as a highly active heterogeneous catalyst for the efficient degradation of sulfathiazole by activation of peroxymonosulfate

In this study, MFe 2 O 4 /WS 2 (M = Co, Cu, Mn, Ni) catalysts were synthesized to activate peroxymonosulfate (PMS) for sulfathiazole (STZ) degradation by decorating with WS 2 on the surface of a series of spinel-type transition metal oxides . It was found that the CoFe 2 O 4 /WS 2 /PMS exhibited a greater ability to degrade sulfathiazole (STZ) than other systems. More specifically, the catalyst facilitated Fe 3+ /Fe 2+ recycling to activate PMS efficiently and maintained synergies between CoFe 2 O 4 and WS 2 to degrade pollutants. The CoFe 2 O 4 /WS 2 dosage, PMS concentration, solution pH, inorganic anions, and natural organic matter, which could affect the catalytic efficiency, were inspected. The experimental results manifested that the catalyst displayed outstanding performance in the pH range from 5 to 9. Besides, electron paramagnetic resonance spectroscopy and radical quenching experiments confirmed the presence of HO•, SO 4 •− , O 2 •− , and 1 O 2 . Based on detected intermediates, the plausible degradation pathway of STZ was proposed.