Feasibility of NDEA formation control from DEDTC in chlorination/chloramination by pre-ozonation: Mechanisms and influencing factors

N-nitrosodiethylamine (NDEA), which is the most toxic nitrosamine among the 9 detected species, has been widely detected in drinking water . Amines containing diethylamine (DEA) groups in the structure would generate NDEA during the disinfection processes. The aim of this study was to evaluate the feasibility of reducing NDEA formation from a commonly used dithiocarbamate pesticide sodium diethyldithiocarbamate (DEDTC) in subsequent chlorination and chloramination by pre-ozonation. The results demonstrated that NDEA could be generated directly during ozonation , its amounts increased from 0 to 14.34 μg/L with increasing ozone dosages (0–4 mg/L), which was higher than that chlorination (2.68 μg/L) and chloramination (4.91 μg/L) when the initial concentration of DEDTC was 20 μM. Pre-ozonation significantly raised NDEA formation from 2.68 to15.32 μg/L in subsequent chlorination; and that from 4.91 to 9.54 μg/L during subsequent chloramination processes. The addition of •OH scavenger tert-butanol (tBA) increased the production of NDEA from 8.14 to 20.80 μg/L during ozonation , and that from 6.76 to17.98 μg/L in O 3 /HClO process, 8.74 to 17.33 μg/L in O 3 /NH 2 Cl process. Except for NO 3 − and CO 3 2− , most of the co-existing substances promoted NDEA generation from DEDTC under disinfection conditions. Based on the results of Gaussian theory calculations, GC/MS and UPLC-Q-TOFMS analysis, the influencing mechanisms of pre-ozonation on NDEA generation in the subsequent disinfection process were proposed. In addition, not only acute/chronic toxicity calculation but also luminescent bacteria test was performed to assess the possibility of pre-ozonation on the risk control of DEDTC. The research results fill a gap in the control of NDEA pollution and help to develop a safer ozone oxidation technology .