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A Novel One-Dimensional Porphyrin-Based Covalent Organic Framework.
Molecules (Basel, Switzerland) [2019-09-19]
PMID: 31527413
ABSTRACT
A novel one-dimensional covalent organic framework (COF-K) was firstly designed and synthesized through a Schiff-based reaction from a porphyrin building block and a nonlinear right-angle building block. The COF-K exhibited high BET surface area and narrow pore size of 1.25 nm and gave a CO2adsorption capacity of 89 mg g−1at 273K and 1bar.Keywords:covalent organic frameworks;one-dimensional structure;porous material
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