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DL-α-Tocopherol methoxypolyethylene glycol succinate , CAS No.1309573-60-1

In stock
Item Number
D431755
Grouped product items
SKU Size
Availability
Price Qty
D431755-1g
1g
Available within 8-12 weeks(?)
Production requires sourcing of materials. We appreciate your patience and understanding.
$100.90
D431755-10g
10g
Available within 8-12 weeks(?)
Production requires sourcing of materials. We appreciate your patience and understanding.
$748.90
D431755-25g
25g
Available within 8-12 weeks(?)
Production requires sourcing of materials. We appreciate your patience and understanding.
$1,324.90
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Basic Description

Synonyms AKOS040744225 | DTXSID301100600 | 1309573-60-1 | TPGS-750-M
Product Description

General Description

Learn More at the Professor and Product Portal of Professor Bruce Lipshutz. We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product TPGS-750-M is a lead surfactant for many transition metal-catalyzed cross-couplings and has been enhanced for catalytic efficiency. Find details here .


Application

On the Way Towards Greener Transition-Metal-Catalyzed Processes as Quantified by E Factors DL-α-Tocopherol methoxypolyethylene glycol succinate (TPGS-750-M), a biodegradable and water-soluble derivative of natural vitamin E, is used as an environmentally benign nonionic surfactant in metal-catalyzed cross-coupling reactions in water. It is used in Heck, Suzuki-Miyaura, Sonogashira, and Negishi like couplings reactions. It can also be utilized in aminations, C-H activations, and olefin metathesis reactions. TPGS-750-M can also be employed in: The nucleophilic aromatic substitution reaction of aryl and heteroaryl halides with nitrogen, oxygen, and sulfur nucleophiles under mild conditions. The preparation of quinoxaline-2,3 diones from quinoxalinones via C(sp 2 )-H hydroxylation reaction. The intramolecular N -arylation of amines using a copper catalyst.


Other Notes

Watch Professor Lipshutz talk about TPGS-750-M in this webinar: From milligrams to kilograms: synthetic chemistry following nature′s lead

Names and Identifiers

IUPAC Name 1-O-(2-methoxyethyl) 4-O-[2,5,7,8-tetramethyl-2-(4,8,12-trimethyltridecyl)-3,4-dihydrochromen-6-yl] butanedioate
INCHI InChI=1S/C36H60O6/c1-25(2)13-10-14-26(3)15-11-16-27(4)17-12-21-36(8)22-20-31-30(7)34(28(5)29(6)35(31)42-36)41-33(38)19-18-32(37)40-24-23-39-9/h25-27H,10-24H2,1-9H3
InChIKey ZMZHTFWPAUPDMZ-UHFFFAOYSA-N
Smiles CC1=C(C(=C(C2=C1OC(CC2)(C)CCCC(C)CCCC(C)CCCC(C)C)C)OC(=O)CCC(=O)OCCOC)C
Isomeric SMILES CC1=C(C(=C(C2=C1OC(CC2)(C)CCCC(C)CCCC(C)CCCC(C)C)C)OC(=O)CCC(=O)OCCOC)C
WGK Germany 2
PubChem CID 149533007
Molecular Weight 588.9

Certificates(CoA,COO,BSE/TSE and Analysis Chart)

C of A & Other Certificates(BSE/TSE, COO):
Analytical Chart:

Chemical and Physical Properties

Flash Point(°F) >230 °F
Flash Point(°C) >110 °C

Solution Calculators

Reviews

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