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Chiralyst Ru928 - 99.95% metals basis, high purity , CAS No.126251-92-1

COA

Grade & Purity:

≥99.95% metals basis

Cas Number: 126251-92-1
Molecular Weight: 827.77
EC Number: 664-455-2
MDL number: MFCD22419153
PubChem CID: 11072956

In stock

Item Number

C294350

Grouped product items
SKU	Size	Availability	Price	Qty
C294350-1g	1g	Available within 8-12 weeks(?) Production requires sourcing of materials. We appreciate your patience and understanding.	$533.90

Discover Chiralyst Ru928 by Aladdin Scientific in 99.95% metals basis for only $533.90. Available - in Ligands at Aladdin Scientific. Tags: .

Basic Description

Synonyms	126251-92-1 \| [RuCl(benzene)(R)-BINAP]Cl \| benzene;chlororuthenium(1+);[1-(2-diphenylphosphanylnaphthalen-1-yl)naphthalen-2-yl]-diphenylphosphane;chloride \| (S)-(+)-2,2/'/'-BIS(DIPHENYLPHOSPHINO)-1,1/'/'-BINAPHTHALENE]CHLORO(BENZENE)RUTHENIUM CHLORIDE \| 124069-39
Specifications & Purity	≥99.95% metals basis
Legal Information	Legal Information Product of Umicore Grubbs Catalyst 为以下机构的注册商标：Umicore
Storage Temp	Room temperature
Shipped In	Normal
Product Description	Product class M-P, Homogeneous Catalysts, M-C, Arene/Aryl Ligands, Phosphorus Ligands - Chiral Reaction type Hydrogenation, Asymmetric Reactions, Asymmetric Hydrogenation, Transfer Hydrogenation Chemical properties Chemical formula C50H38Cl2P2Ru Empirical formula [RuCl(benzene)(S)-BINAP)]Cl Molecular weight 827.77 Metal Ru Theoretical metal content 12 Physical state powder Color yellow Metal purity 99.95 Applications & references Synthesis of α-arylpropionic acids by catalytic asymmetrical hydrogenation of α-arylpropenioc acids starting from α-arylketones. Reference: WO1992 09552 Asymmetric hydrogenation of a five-membred α,ß-unsaturated carbonyl component. Reference: J. Org. Chem. 1995, 60, 857 (DOI: 10.1021/jo00107a014) Asymmetric hydrogenation of a functionalized diketone. Reference: J. Org. Chem. 1995, 60, 857 (DOI: 10.1021/jo00107a014) Asymmetric hydrogenation of α-ketoester. Reference: J. Org. Chem. 1994, 59, 3064 (DOI: 10.1021/jo00090a026) Oxidation of cis-1,2-cyclohexanedimethanol by hydrogen transfer reaction. Reference: J. Organomet. Chem. 1994, 473, 253 (DOI: 10.1016/0022-328X(94)80125-8)

Names and Identifiers

IUPAC Name	benzene;chlororuthenium(1+);[1-(2-diphenylphosphanylnaphthalen-1-yl)naphthalen-2-yl]-diphenylphosphane;chloride
INCHI	InChI=1S/C44H32P2.C6H6.2ClH.Ru/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38;1-2-4-6-5-3-1;;;/h1-32H;1-6H;2*1H;/q;;;;+2/p-2
InChIKey	ZXBWEYDPYJZEFT-UHFFFAOYSA-L
Smiles	C1=CC=CC=C1.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=C(C4=CC=CC=C4C=C3)C5=C(C=CC6=CC=CC=C65)P(C7=CC=CC=C7)C8=CC=CC=C8.[Cl-].Cl[Ru+]
Isomeric SMILES	C1=CC=CC=C1.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=C(C4=CC=CC=C4C=C3)C5=C(C=CC6=CC=CC=C65)P(C7=CC=CC=C7)C8=CC=CC=C8.[Cl-].Cl[Ru+]
PubChem CID	11072956
Molecular Weight	827.77

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