Basic Description

Synonyms	MCQRPQCQMGVWIQ-UHFFFAOYSA-N \| Dimethyl sulphide borane \| Dimethyl sulfide borane \| borane methylsulphide \| boron dimethyl sulfide \| FT-0652013 \| Borane dimethyl sulfide complex 2.0 M in THF \| UNII-93TWS7F2GX \| (Dimethyl sulfide)trihydroboron \| (Methylthio
Specifications & Purity	9.8M in Dimethylthioamidine
Storage Temp	Store at 2-8°C,Argon charged
Shipped In	Wet ice This product requires cold chain shipping. Ground and other economy services are not available.
Product Description	Borane dimethyl sulfide complex (BMS) is a commonly used reagent and a mediator for hydroboration reaction for the preparation of organoborane compounds, which are utilized as key intermediates in organic synthesis. BMS is also employed as a reducing agent for the reduction of various functional groups such as aldehydes, ketones, epoxides, esters, and carboxylic acids to corresponding alcohols. Application Borane-dimethyl sulfide (BH 3 Me 2 S) can be used as a reagent: For the selective synthesis of 1,3,5-oxygenated compounds from dimethyl 3-oxoglutarate. For the conversion of ozonides to alcohols. In the CBS-catalyzed asymmetric reduction of ferrocenyl-1,3-diketones to 1,3-diols. For enantioselective reduction of ketones to chiral secondary alcohols in the presence of C 3 -symmetric tripodal hydroxyamide as a ligand. For the hydroboration reduction and other applications. With a dendrimeric supported L-pyrrolidinol in the asymmetric reduction of indanones and tetralones. Other Notes 10.0-10.2 M as BH 3 . May contain excess methyl sulfide.

Taxonomic Classification

Taxonomy Tree

Kingdom Organic compounds
- Superclass Organic salts
  - Class Organic metal salts
    - Subclass Organic metalloid salts

Kingdom	Organic compounds
Superclass	Organic salts
Class	Organic metal salts
Subclass	Organic metalloid salts
Intermediate Tree Nodes	Not available
Direct Parent	Organic metalloid salts
Alternative Parents	Sulfenyl compounds Dialkylthioethers Hydrocarbon derivatives
Molecular Framework	Aliphatic acyclic compounds
Substituents	Organic metalloid salt - Dialkylthioether - Sulfenyl compound - Thioether - Hydrocarbon derivative - Organosulfur compound - Aliphatic acyclic compound
Description	This compound belongs to the class of organic compounds known as organic metalloid salts. These are organic salt compounds containing a metalloid atom in its ionic form.
External Descriptors	Not available
1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61. DOI: 10.1186/s13321-016-0174-y

Names and Identifiers

INCHI	InChI=1S/C2H6S.B/c1-3-2;/h1-2H3;
InChIKey	MCQRPQCQMGVWIQ-UHFFFAOYSA-N
Smiles	[B].CSC
Isomeric SMILES	[B].CSC
WGK Germany	3
Molecular Weight	75.97
Beilstein	3663489
Reaxy-Rn	14759666
Reaxys-RN_link_address	https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=14759666&ln=

Certificates（CoA,COO,BSE/TSE and Analysis Chart)

C of A & Other Certificates(BSE/TSE, COO):

Analytical Chart:

Find and download the COA for your product by matching the lot number on the packaging.

3 results found

Lot Number	Certificate Type	Date	Item
B2427026	Certificate of Analysis	Jan 19, 2024	B431899
B2427025	Certificate of Analysis	Jan 19, 2024	B431899
B2427024	Certificate of Analysis	Jan 19, 2024	B431899

Chemical and Physical Properties

Molecular Weight	72.950 g/mol
XLogP3
Hydrogen Bond Donor Count	0
Hydrogen Bond Acceptor Count	1
Rotatable Bond Count	0
Exact Mass	73.0283 Da
Monoisotopic Mass	73.0283 Da
Topological Polar Surface Area	25.300 Å²
Heavy Atom Count	4
Formal Charge	0
Complexity	2.800
Isotope Atom Count	0
Defined Atom Stereocenter Count	0
Undefined Atom Stereocenter Count	0
Defined Bond Stereocenter Count	0
Undefined Bond Stereocenter Count	0
The total count of all stereochemical bonds	0
Covalently-Bonded Unit Count	2

Documents & Articles

Boranes (Dimethylsulfide Borane, Borane-Tetrahydrofuran Complex)

Categories: Technical articles

Tags:

Reducing agent C-H Functionalization Boronic Acids and Derivatives Boranes

Citations of This Product

How to Cite Aladdin Scientific Products?

1. Shibin Wu, Keru Song, Jianwen Wang, Siyu Huang, Fengyue Shi, Guangdong Zhao. (2023) Microstructure and phase evolution behavior of SiZrBC ceramic precursors synthesized via sol–gel method. JOURNAL OF SOLID STATE CHEMISTRY, 321 (123910).
2. Hui-Ling Duan, Xu Deng, Jun Wang, Li Fan, Yu-Cheng Yang, Zhi-Qi Zhang. (2020) Ethanolamine- and amine-functionalized porous cyclodextrin polymers for efficient removal of anionic dyes from water. EUROPEAN POLYMER JOURNAL, 133 (109762).

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SKU	Size	Availability	Price
B431899-25ml	25ml	Available within 8-12 weeks(?) Production requires sourcing of materials. We appreciate your patience and understanding.	$145.90
B431899-4×25ml	4×25ml	Available within 8-12 weeks(?) Production requires sourcing of materials. We appreciate your patience and understanding.	$525.90
B431899-500ml	500ml	Available within 8-12 weeks(?) Production requires sourcing of materials. We appreciate your patience and understanding.	$1,118.90

Borane dimethyl sulfide complex - 9.8M in Dimethylthioamidine, high purity , CAS No.13292-87-0(Dimethylthioamidine)