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Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate - 99.95% metals basis, high purity , CAS No.99326-34-8

COA

Grade & Purity:

≥99.95% metals basis

Cas Number: 99326-34-8
Molecular Weight: 468.34
MDL number: MFCD00143752
PubChem CID: 5702638

In stock

Item Number

B284034

Grouped product items
SKU	Size	Availability	Price
B284034-250mg	250mg	Available within 8-12 weeks(?) Production requires sourcing of materials. We appreciate your patience and understanding.	$281.90
B284034-1g	1g	Available within 8-12 weeks(?) Production requires sourcing of materials. We appreciate your patience and understanding.	$817.90
B284034-5g	5g	Available within 8-12 weeks(?) Production requires sourcing of materials. We appreciate your patience and understanding.	$2,859.90

Discover Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate by Aladdin Scientific in 99.95% metals basis for only $281.90. Available - in Ligands at Aladdin Scientific. Tags: .

Basic Description

Synonyms	Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate \| 99326-34-8 \| [rh(cod)2]otf \| (1Z,5Z)-cycloocta-1,5-diene;rhodium;trifluoromethanesulfonate \| Bis(1,5-cyclooctadiene)rhodium(I)trifluoromethanesulfonate \| MFCD00143752 \| Rh(cod)2OTf \| Bis(1,5-cyclooctadiene)r
Specifications & Purity	≥99.95% metals basis
Legal Information	Product of Umicore
Storage Temp	Room temperature,Argon charged
Shipped In	Normal
Product Description	Application Precatalysts for Asymmetric and Cross-Coupling Catalysis Product class M-C, Homogeneous Catalysts, Diene/Dienyl Ligands Reaction type Hydrogenation, Asymmetric Reactions, CH-Activation, Hydroformylation, Asymmetric Hydrogenation Chemical properties Chemical formula C17H24F3O3SRh Empirical formula [Rh(cod)2]CF3SO3 Molecular weight 468.34 Metal Rh Theoretical metal content 22 Physical state crystalline Color red Metal purity 99.95

Taxonomic Classification

Taxonomy Tree

Kingdom Organic compounds
- Superclass Organic acids and derivatives
  - Class Organic sulfonic acids and derivatives
    - Subclass Organosulfonic acids and derivatives
      - Level5 Alkanesulfonic acids and derivatives
        Level6 Alkanesulfonic acids
        Level7 Trifluoromethanesulfonates

Kingdom	Organic compounds
Superclass	Organic acids and derivatives
Class	Organic sulfonic acids and derivatives
Subclass	Organosulfonic acids and derivatives
Intermediate Tree Nodes	Alkanesulfonic acids and derivatives - Alkanesulfonic acids
Direct Parent	Trifluoromethanesulfonates
Alternative Parents	Sulfonyls Organosulfonic acids Methanesulfonates Trihalomethanes Organic transition metal salts Cycloalkenes Unsaturated aliphatic hydrocarbons Organofluorides Organic oxides Hydrocarbon derivatives Alkyl fluorides Organic anions
Molecular Framework	Not available
Substituents	Trifluoromethanesulfonate - Methanesulfonate - Organosulfonic acid - Sulfonyl - Trihalomethane - Cyclic olefin - Cycloalkene - Organic transition metal salt - Alkyl fluoride - Alkyl halide - Organic oxygen compound - Hydrocarbon derivative - Halomethane - Organic oxide - Organosulfur compound - Organofluoride - Organohalogen compound - Olefin - Unsaturated hydrocarbon - Unsaturated aliphatic hydrocarbon - Organic anion - Hydrocarbon - Aliphatic homomonocyclic compound
Description	This compound belongs to the class of organic compounds known as trifluoromethanesulfonates. These are alkanesulfonic acids, that contain a sulfonate group that is substituted with a trifluoromethyl group.
External Descriptors	Not available
1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61. DOI: 10.1186/s13321-016-0174-y

Names and Identifiers

IUPAC Name	(1Z,5Z)-cycloocta-1,5-diene;rhodium;trifluoromethanesulfonate
INCHI	InChI=1S/2C8H12.CHF3O3S.Rh/c21-2-4-6-8-7-5-3-1;2-1(3,4)8(5,6)7;/h21-2,7-8H,3-6H2;(H,5,6,7);/p-1/b2*2-1-,8-7-;;
InChIKey	VUTUHLLWFPRWMT-QMDOQEJBSA-M
Smiles	C1CC=CCCC=C1.C1CC=CCCC=C1.C(F)(F)(F)S(=O)(=O)[O-].[Rh]
Isomeric SMILES	C1/C=C\CC/C=C\C1.C1/C=C\CC/C=C\C1.C(S(=O)(=O)[O-])(F)(F)F.[Rh]
WGK Germany	3
PubChem CID	5702638
Molecular Weight	468.34

Certificates（CoA,COO,BSE/TSE and Analysis Chart)

C of A & Other Certificates(BSE/TSE, COO):

Analytical Chart:

Chemical and Physical Properties

Solubility	Soluble in chloroform
Sensitivity	Air Sensitive
Melt Point(°C)	159°C
Molecular Weight	468.300 g/mol
XLogP3
Hydrogen Bond Donor Count	0
Hydrogen Bond Acceptor Count	6
Rotatable Bond Count	0
Exact Mass	468.045 Da
Monoisotopic Mass	468.045 Da
Topological Polar Surface Area	65.600 Å²
Heavy Atom Count	25
Formal Charge	-1
Complexity	217.000
Isotope Atom Count	0
Defined Atom Stereocenter Count	0
Undefined Atom Stereocenter Count	0
Defined Bond Stereocenter Count	4
Undefined Bond Stereocenter Count	0
The total count of all stereochemical bonds	4
Covalently-Bonded Unit Count	4

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