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2-Chlorophenylzinc iodide solution - 0.5M in THF, high purity , CAS No.148651-35-8

    Grade & Purity:
  • 0.5M in THF
In stock
Item Number
C465891
Grouped product items
SKU Size
Availability
Price Qty
C465891-50ml
50ml
Available within 8-12 weeks(?)
Production requires sourcing of materials. We appreciate your patience and understanding.
$912.90

Basic Description

Specifications & Purity 0.5M in THF
Legal Information Rieke® Metals, Inc. 产品 ®Rieke Metals, Inc. 的注册商标Rieke is a registered trademark of Rieke Metals, Inc.
Storage Temp Store at 2-8°C,Argon charged
Shipped In
Wet ice
This product requires cold chain shipping. Ground and other economy services are not available.
Product Description

Description

2-Chlorophenylzinc iodide is an organozinc compound, which can be used as a reactant in Negishi cross-coupling reaction to construct carbon-carbon bonds by reacting with organic halides using nickel or palladium catalysts.It can also be utilized as a reactant to prepare:Arylmethanes via rhodium-catalyzed cross-coupling reaction with methyl halides.(2-chlorobenzyl)trimethylsilane by Rh-catalyzed cross-coupling reaction with (iodomethyl)trimethylsilane.Dichloro biphenyl by palladium catalyzed oxidative homocoupling reaction usingN-chlorosuccinimide (NCS) or O2as the oxidant.

Taxonomic Classification

Taxonomy Tree

Kingdom Organic compounds
Superclass Benzenoids
Class Benzene and substituted derivatives
Subclass Halobenzenes
Intermediate Tree Nodes Not available
Direct Parent Chlorobenzenes
Alternative Parents Aryl chlorides  Organic transition metal salts  Organic metal halides  Organochlorides  Hydrocarbon derivatives  Organic cations  
Molecular Framework Aromatic homomonocyclic compounds
Substituents Chlorobenzene - Aryl halide - Aryl chloride - Organic metal halide - Organic metal salt - Organic transition metal salt - Hydrocarbon derivative - Organic salt - Organochloride - Organohalogen compound - Organic cation - Aromatic homomonocyclic compound
Description This compound belongs to the class of organic compounds known as chlorobenzenes. These are compounds containing one or more chlorine atoms attached to a benzene moiety.
External Descriptors Not available

Names and Identifiers

IUPAC Name chlorobenzene;iodozinc(1+)
INCHI InChI=1S/C6H4Cl.HI.Zn/c7-6-4-2-1-3-5-6;;/h1-4H;1H;/q-1;;+2/p-1
InChIKey NNTCIUUTIPRDJR-UHFFFAOYSA-M
Smiles C1=CC=C([C-]=C1)Cl.[Zn+]I
Isomeric SMILES C1=CC=C([C-]=C1)Cl.[Zn+]I
PubChem CID 4185004
UN Number 2056
Molecular Weight 303.84

Certificates(CoA,COO,BSE/TSE and Analysis Chart)

C of A & Other Certificates(BSE/TSE, COO):
Analytical Chart:

Chemical and Physical Properties

Sensitivity Heat sensitive
Flash Point(°F) 1.0 °F - closed cup
Flash Point(°C) -17.22 °C - closed cup
Molecular Weight 303.800 g/mol
XLogP3
Hydrogen Bond Donor Count 0
Hydrogen Bond Acceptor Count 1
Rotatable Bond Count 0
Exact Mass 301.834 Da
Monoisotopic Mass 301.834 Da
Topological Polar Surface Area 0.000 Ų
Heavy Atom Count 9
Formal Charge 0
Complexity 149.000
Isotope Atom Count 0
Defined Atom Stereocenter Count 0
Undefined Atom Stereocenter Count 0
Defined Bond Stereocenter Count 0
Undefined Bond Stereocenter Count 0
The total count of all stereochemical bonds 0
Covalently-Bonded Unit Count 2

Solution Calculators

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