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2-Bromoacetophenone - for GC derivatization, ≥99.0%, high purity , CAS No.70-11-1

In stock
Item Number
B131582
Grouped product items
SKU Size
Availability
Price Qty
B131582-5g
5g
Available within 8-12 weeks(?)
Production requires sourcing of materials. We appreciate your patience and understanding.
$105.90
B131582-25g
25g
3
$343.90

Basic Description

Synonyms 2-Bromoacetophenone | 70-11-1 | Phenacyl bromide | 2-Bromo-1-phenylethanone | Bromoacetophenone | Ethanone, 2-bromo-1-phenyl- | Bromomethyl phenyl ketone | 2-Bromo-1-Phenylethan-1-One | ALPHA-BROMOACETOPHENONE | omega-Bromoacetophenone | Acetophenone, 2-bromo- | Stauffer 4644 |
Specifications & Purity for GC derivatization, ≥99%
Storage Temp Store at 2-8°C,Argon charged
Shipped In
Wet ice
This product requires cold chain shipping. Ground and other economy services are not available.
Grade for GC derivatization
Product Description

2-Bromoacetophenone has been used in the analysis of organic acids involving the formation of phenacyl derivatives.

Taxonomic Classification

Taxonomy Tree

Kingdom Organic compounds
Superclass Organic oxygen compounds
Class Organooxygen compounds
Subclass Carbonyl compounds
Intermediate Tree Nodes Ketones - Aryl ketones - Phenylketones
Direct Parent Alkyl-phenylketones
Alternative Parents Benzoyl derivatives  Aryl alkyl ketones  Alpha-haloketones  Organobromides  Organic oxides  Hydrocarbon derivatives  Alkyl bromides  
Molecular Framework Aromatic homomonocyclic compounds
Substituents Alkyl-phenylketone - Aryl alkyl ketone - Benzoyl - Benzenoid - Monocyclic benzene moiety - Alpha-haloketone - Organic oxide - Hydrocarbon derivative - Organobromide - Organohalogen compound - Alkyl halide - Alkyl bromide - Aromatic homomonocyclic compound
Description This compound belongs to the class of organic compounds known as alkyl-phenylketones. These are aromatic compounds containing a ketone substituted by one alkyl group, and a phenyl group.
External Descriptors alpha-bromoketone - aromatic ketone - acetophenones

Associated Targets(Human)

GSK3B Tclin Glycogen synthase kinase-3 beta (11785 Activities)
Activity Type Relation Activity value Units Action Type Journal PubMed Id doi Assay Aladdin ID
CTSB Tchem Cathepsin B (3822 Activities)
Activity Type Relation Activity value Units Action Type Journal PubMed Id doi Assay Aladdin ID

Associated Targets(non-human)

Ptpn1 Protein-tyrosine phosphatase 1B (270 Activities)
Activity Type Relation Activity value Units Action Type Journal PubMed Id doi Assay Aladdin ID

Mechanisms of Action

Mechanism of Action Action Type target ID Target Name Target Type Target Organism Binding Site Name References

Names and Identifiers

Pubchem Sid 504751042
Pubchem Sid Url https://pubchem.ncbi.nlm.nih.gov/substance/504751042
IUPAC Name 2-bromo-1-phenylethanone
INCHI InChI=1S/C8H7BrO/c9-6-8(10)7-4-2-1-3-5-7/h1-5H,6H2
InChIKey LIGACIXOYTUXAW-UHFFFAOYSA-N
Smiles C1=CC=C(C=C1)C(=O)CBr
Isomeric SMILES C1=CC=C(C=C1)C(=O)CBr
WGK Germany 3
UN Number 2645
Packing Group II
Molecular Weight 199.04
Beilstein 606474
Reaxy-Rn 606474
Reaxys-RN_link_address https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=606474&ln=

Certificates(CoA,COO,BSE/TSE and Analysis Chart)

C of A & Other Certificates(BSE/TSE, COO):
Analytical Chart:

Find and download the COA for your product by matching the lot number on the packaging.

9 results found

Lot Number Certificate Type Date Item
F2509111 Certificate of Analysis Jul 30, 2024 B131582
H2406370 Certificate of Analysis Jul 30, 2024 B131582
H2406371 Certificate of Analysis Jul 30, 2024 B131582
L1814001 Certificate of Analysis Oct 17, 2022 B131582
C2412055 Certificate of Analysis Jun 04, 2022 B131582
F2223184 Certificate of Analysis Jun 04, 2022 B131582
F2223185 Certificate of Analysis Jun 04, 2022 B131582
E2224035 Certificate of Analysis Mar 18, 2022 B131582
E2224036 Certificate of Analysis Mar 18, 2022 B131582

Chemical and Physical Properties

Sensitivity Light & Heat & Air sensitive.
Refractive Index 1.709
Flash Point(°F) 235.4 °F
Flash Point(°C) 113 °C
Boil Point(°C) 135 °C/18 mmHg
Melt Point(°C) 51°C
Molecular Weight 199.040 g/mol
XLogP3 2.500
Hydrogen Bond Donor Count 0
Hydrogen Bond Acceptor Count 1
Rotatable Bond Count 2
Exact Mass 197.968 Da
Monoisotopic Mass 197.968 Da
Topological Polar Surface Area 17.100 Ų
Heavy Atom Count 10
Formal Charge 0
Complexity 116.000
Isotope Atom Count 0
Defined Atom Stereocenter Count 0
Undefined Atom Stereocenter Count 0
Defined Bond Stereocenter Count 0
Undefined Bond Stereocenter Count 0
The total count of all stereochemical bonds 0
Covalently-Bonded Unit Count 1

Citations of This Product

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2. Juncao Hou, Jihong Xu, Rui Tang, Yulin Min, Sukum Eitssayeam, Penghui Shi.  (2023)  Activation of peracetic acid by biochar for sulfamethoxazole degradation: Revealing roles of the active sites.  Journal of the Taiwan Institute of Chemical Engineers,  152  (105184). 
3. Meiling Chen, Lin Ding, Shijun Zhu, Xiuqin Xiong, Xinkai Yuan, Yanhua Peng, Liming Yang, Hui Shi, Penghui Shao, Xubiao Luo.  (2023)  Decomplexation of Ni-EDTA enhanced by Fe(III) reduction in the Fenton reaction: Insight into the role of carbonyl groups.  Journal of Environmental Chemical Engineering,  11  (111097). 
4. Xuyi Li, Chen Huang, Yu Fan, Zhiang Bai, Bao-Li An, Jiaqiang Xu, Weiwei Zheng, Yue-Ling Bai.  (2023)  Boosting Solid-State Luminescence of Thiazolothiazole Viologen by Incorporating Metal Halide Clusters to Hinder π-Stacking.  ACS Applied Materials & Interfaces,  15  (39): (46022–46030). 
5. Lixia Li, Zhechao Huang, Fenghao Shu, Ying Gao, Jinxing Long.  (2024)  Hydrodeoxygenation of heavy lignin bio-oil to oxygenated fuel catalyzed by CuxNiy/MgO.  FUEL,  357  (129805). 
6. Xin Lv, Chenying Zhou, Zhichao Shen, Yuchen Zhang, Chuanshu He, Ye Du, Zhaokun Xiong, Rongfu Huang, Peng Zhou, Bo Lai.  (2023)  Waste leather derived porous carbon boosted Fenton oxidation towards removal of diethyl phthalate: Mechanism and long-lasting performance.  JOURNAL OF HAZARDOUS MATERIALS,  458  (132040). 
7. Liang Wenfei, Nie Chengming, Du Jun, Han Yaoyao, Zhao Guohui, Yang Fan, Liang Guijie, Wu Kaifeng.  (2023)  Near-infrared photon upconversion and solar synthesis using lead-free nanocrystals.  Nature Photonics,  17  (4): (346-353). 
8. Bo Kong, Tong Yang, Feng Cheng, Yan Qian, Chunmei Li, Lei Zhan, Yuanfang Li, Hongyan Zou, Chengzhi Huang.  (2022)  Carbon dots as nanocatalytic medicine for anti-inflammation therapy.  JOURNAL OF COLLOID AND INTERFACE SCIENCE,  611  (545). 
9. Chenying Zhou, Peng Zhou, Minglu Sun, Yang Liu, Heng Zhang, Zhaokun Xiong, Juan Liang, Xiaoguang Duan, Bo Lai.  (2022)  Nitrogen-doped carbon nanotubes enhanced Fenton chemistry: Role of near-free iron(III) for sustainable iron(III)/iron(II) cycles.  WATER RESEARCH,  210  (117984). 
10. Jun-Nan Yang, Tian Chen, Jing Ge, Jing-Jing Wang, Yi-Chen Yin, Yi-Feng Lan, Xue-Chen Ru, Zhen-Yu Ma, Qun Zhang, Hong-Bin Yao.  (2021)  High Color Purity and Efficient Green Light-Emitting Diode Using Perovskite Nanocrystals with the Size Overly Exceeding Bohr Exciton Diameter.  Journal of the American Chemical Society,  143  (47): (19928–19937). 
11. Qingmeng Dong, Zhouqi Tian, Wulin Song, Weiping Deng, Hongxi Zhang.  (2021)  Catalytic oxidation of lignin and model compounds over nano europium oxide.  COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,  626  (126846). 
12. Fei Zhang, Yaoming Liu, Binsheng Yang, Guangming Wen, Bin Liu.  (2020)  Near-infrared AIEgens for lipid droplets imaging in corpus adiposum or trachea of Locusta migratoria and its application in photodynamic therapy.  SENSORS AND ACTUATORS B-CHEMICAL,  322  (128589). 
13. Guozhi Zhu, Song Shi, Li Zhao, Meng Liu, Jin Gao, Jie Xu.  (2020)  Catalytic Activation of Carbon–Hydrogen Bonds in Lignin Linkages over Strong-Base-Modified Covalent Triazine Frameworks for Lignin Oxidative Cleavage.  ACS Catalysis,  10  (14): (7526–7534). 
14. Bingxing Jiang, Jun Hu, Yiheng Qiao, Xiaoxiang Jiang, Ping Lu.  (2019)  Depolymerization of Lignin over a Ni–Pd Bimetallic Catalyst Using Isopropanol as an in Situ Hydrogen Source.  ENERGY & FUELS,  33  (9): (8786–8793). 
15. Weixiang Guan, Chuang Li, Xiao Chen, Xiao-Ying Lu, Chi-Wing Tsang, Haoquan Hu, Hongxu Qi, Changhai Liang.  (2019)  Tuning the Acidity of Pt/ CNTs Catalysts for Hydrodeoxygenation of Diphenyl Ether.  Jove-Journal of Visualized Experiments,    (150): (e59870). 
16. Da Wang, Yuyang Wang, Xiaoyu Li, Lei Chen, Guangci Li, Xuebing Li.  (2018)  Lignin Valorization: A Novel in Situ Catalytic Hydrogenolysis Method in Alkaline Aqueous Solution.  ENERGY & FUELS,  32  (7): (7643–7651). 
17. Li Zhao, Song Shi, Meng Liu, Guozhi Zhu, Min Wang, Wenqiang Du, Jin Gao, Jie Xu.  (2018)  Covalent triazine framework catalytic oxidative cleavage of lignin models and organosolv lignin.  GREEN CHEMISTRY,  20  (6): (1270-1279). 
18. T. M. Chen, X. M. Tian, L. Huang, J. Xiao, G. W. Yang.  (2017)  Nanodiamonds as pH-switchable oxidation and reduction catalysts with enzyme-like activities for immunoassay and antioxidant applications.  Nanoscale,  (40): (15673-15684). 
19. Xuyi Li, Chen Huang, Rui Xue, Jia-Ping Tong, Yuehan Cheng, Bao-Li An, Jiaqiang Xu, Yue-Ling Bai.  (2024)  A Viologen Derivative Transition from Photosilence to Sensitive Photochromism through Ion Exchange.  CRYSTAL GROWTH & DESIGN,     
20. Jingyi Wu, Jialin Zhao, Na Li, Yijia Lei, Yan Wang, Song Wang, Yiman Gu, Yanchao Zhang, Junjian Yu, Jian Gao, Zhanyu Li, Zhe Wang.  (2024)  High mechanical performance Brominated Poly(aryl piperidinium) anion exchange membranes based on non-covalent crosslinking.  INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,  62  (1043). 
21. Xinjie Li, Linqi Chen, Danqun Mao, Jingzhou Li, Wei Xie, Hongxing Dong, Long Zhang.  (2024)  Low-threshold cavity-enhanced superfluorescence in polyhedral quantum dot superparticles.  Nanoscale Advances,  (12): (3220-3228). 

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