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2,2,2-Trifluoroethyl methacrylate - Electronic grade,99.9999% metals basis, high purity , CAS No.352-87-4

In stock
Item Number
T299433
Grouped product items
SKU Size
Availability
Price Qty
T299433-5ml
5ml
5
$34.90
T299433-25ml
25ml
3
$123.90
T299433-100ml
100ml
Available within 4-8 weeks(?)
Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!
$343.90

Basic Description

Synonyms 2,2,2-TRIFLUOROETHYL METHACRYLATE | 352-87-4 | Trifluoroethyl methacrylate | 2,2,2-trifluoroethyl 2-methylprop-2-enoate | 54802-79-8 | 2-Propenoic acid, 2-methyl-, trifluoroethyl ester | Methacrylic acid 2,2,2-trifluoroethyl ester | 2-Propenoic acid, 2-methyl-, 2,2,2-t
Specifications & Purity PrimorTrace™ Ultra, electronic grade, ≥99.9999% metals basis
Storage Temp Store at 2-8°C,Protected from light
Shipped In
Wet ice
This product requires cold chain shipping. Ground and other economy services are not available.
Grade electronic grade, PrimorTrace™ Ultra

Taxonomic Classification

Taxonomy Tree

Kingdom Organic compounds
Superclass Organic acids and derivatives
Class Carboxylic acids and derivatives
Subclass Carboxylic acid derivatives
Intermediate Tree Nodes Carboxylic acid esters - Alpha,beta-unsaturated carboxylic esters
Direct Parent Enoate esters
Alternative Parents Monocarboxylic acids and derivatives  Organofluorides  Organic oxides  Hydrocarbon derivatives  Carbonyl compounds  Alkyl fluorides  
Molecular Framework Aliphatic acyclic compounds
Substituents Enoate ester - Monocarboxylic acid or derivatives - Organic oxygen compound - Organic oxide - Hydrocarbon derivative - Organooxygen compound - Organofluoride - Organohalogen compound - Carbonyl group - Alkyl halide - Alkyl fluoride - Aliphatic acyclic compound
Description This compound belongs to the class of organic compounds known as enoate esters. These are an alpha,beta-unsaturated carboxylic ester of general formula R1C(R2)=C(R3)C(=O)OR4 (R4= organyl compound) in which the ester C=O function is conjugated to a C=C double bond at the alpha,beta position.
External Descriptors Not available

Names and Identifiers

Pubchem Sid 504751852
Pubchem Sid Url https://pubchem.ncbi.nlm.nih.gov/substance/504751852
IUPAC Name 2,2,2-trifluoroethyl 2-methylprop-2-enoate
INCHI InChI=1S/C6H7F3O2/c1-4(2)5(10)11-3-6(7,8)9/h1,3H2,2H3
InChIKey QTKPMCIBUROOGY-UHFFFAOYSA-N
Smiles CC(=C)C(=O)OCC(F)(F)F
Isomeric SMILES CC(=C)C(=O)OCC(F)(F)F
WGK Germany 2
UN Number 3272
Molecular Weight 168.11
Reaxy-Rn 4175872

Certificates(CoA,COO,BSE/TSE and Analysis Chart)

C of A & Other Certificates(BSE/TSE, COO):
Analytical Chart:

Find and download the COA for your product by matching the lot number on the packaging.

3 results found

Lot Number Certificate Type Date Item
D2112139 Certificate of Analysis Aug 04, 2023 T299433
D2112140 Certificate of Analysis Aug 04, 2023 T299433
D2112141 Certificate of Analysis Aug 04, 2023 T299433

Chemical and Physical Properties

Sensitivity Heat and Light Sensitive
Refractive Index n20/D 1.361
Flash Point(°F) 77 °F
Flash Point(°C) 25°C
Boil Point(°C) 59 °C/100 mmHg
Molecular Weight 168.110 g/mol
XLogP3 2.700
Hydrogen Bond Donor Count 0
Hydrogen Bond Acceptor Count 5
Rotatable Bond Count 3
Exact Mass 168.04 Da
Monoisotopic Mass 168.04 Da
Topological Polar Surface Area 26.300 Ų
Heavy Atom Count 11
Formal Charge 0
Complexity 171.000
Isotope Atom Count 0
Defined Atom Stereocenter Count 0
Undefined Atom Stereocenter Count 0
Defined Bond Stereocenter Count 0
Undefined Bond Stereocenter Count 0
The total count of all stereochemical bonds 0
Covalently-Bonded Unit Count 1

Citations of This Product

1. Zuowei Zhang, Xian He, Luoning Zhang, Jianjun Xu, Baohua Yuan, Chao Chen, Cheng Zou, Qian Wang, Yanzi Gao, Meina Yu, Huai Yang.  (2024)  A novel low-voltage fast-response electrically controlled dimming film based on fluorinated PDLC for smart window applications.  CHEMICAL ENGINEERING JOURNAL,  479  (147668). 
2. Min Li, Honglang Lu, Menghan Pi, Hui Zhou, Yufei Wang, Bin Yan, Wei Cui, Rong Ran.  (2023)  Water-Induced Phase Separation for Anti-Swelling Hydrogel Adhesives in Underwater Soft Electronics.  Advanced Science,    (2304780). 
3. Yutuo Wang, Mengqing Xiao, Changwen Chen, Yintao Li, Zhengquan Zhang, Yuanlin Zhou, Shanqiang Wang.  (2023)  Preparation and performance study of the self-brittle composite detergent with controllable morphology for radioactive decontamination of surface layer of various materials by RAFT one-pot synthesis.  REACTIVE & FUNCTIONAL POLYMERS,  187  (105591). 
4. Yaling Lin, Deqiang Zhang, Shijie Shan, Wei Zhang, Rui Li, Anqiang Zhang.  (2023)  Fluorine-containing amphiphilic quaternary ammonium salts for the suppression of Banana fusarium wilt.  REACTIVE & FUNCTIONAL POLYMERS,  182  (105488). 
5. Junzhi Lin, Xianger Xia, Yifei Liu, Zhenchao Luan, Yezhen Chen, Kunkai Ma, Bing Geng, Hui Li.  (2022)  Fabrication of hierarchical porous fluoro-PolyHIPE materials with ultra-high specific surface area via hypercrosslinking knitting technique.  JOURNAL OF APPLIED POLYMER SCIENCE,  139  (38): (e52914). 
6. Jie Liu, Jiawen Sun, Jizhou Duan, Xucheng Dong, Xinping Wang, Chao Liu, Baorong Hou.  (2022)  Capsaicin-Modified Fluorosilicone Based Acrylate Coating for Marine Anti-Biofouling.  Coatings,  12  (7): (988). 
7. Liu Yuncong, Chen Tao, Jin Zhekai, Li Mengxue, Zhang Dongdong, Duan Lian, Zhao Zhiguo, Wang Chao.  (2022)  Tough, stable and self-healing luminescent perovskite-polymer matrix applicable to all harsh aquatic environments.  Nature Communications,  13  (1): (1-11). 
8. Zhongqiang Yu, Wen Sun, Lida Wang, Zhengqing Yang, Han Zhang, Guichang Liu, Qian Zhang.  (2022)  Excellent synergistic antifouling polymers based on controlled release of cinnamic acid and hydrolysis-induced fluorinated micro/nanostructure.  MATERIALS CHEMISTRY AND PHYSICS,  282  (125913). 
9. Qiumeng Chen, Yahui Li, Ming Liu, Xuan Wu, Jianliang Shen, Liangliang Shen.  (2021)  Constructing helical nanowires via polymerization-induced self-assembly.  RSC Advances,  11  (15): (8986-8992). 
10. Hailiang Liu, Yueming Liu, Yang Qin, Yan Huang, Kaikai Chen, Changfa Xiao.  (2021)  Amphiphilic surface construction and properties of PVC-g-PPEGMA/PTFEMA graft copolymer membrane.  APPLIED SURFACE SCIENCE,  545  (148985). 
11. Jian Lu, Ying-Ying Qin, Yi-Lin Wu, Mu-Ning Chen, Chang Sun, Zi-Xuan Han, Yong-Sheng Yan, Chun-Xiang Li, Yan Yan.  (2021)  Mimetic-core-shell design on molecularly imprinted membranes providing an antifouling and high-selective surface.  CHEMICAL ENGINEERING JOURNAL,  417  (128085). 
12. Yi-Feng Liu, Hong-Rui Wang, Jiang-Yu Li, Meng-Jie Chen, Hui Chen, Bing-Yi Lu, Qiang Ma, Xiong-Wei Wu, Xian-Xiang Zeng.  (2021)  Mixed lithium fluoride-nitride ionic conducting interphase for dendrite-free lithium metal anode.  APPLIED SURFACE SCIENCE,  541  (148294). 
13. Jihong Liang, Umair Azhar, Pengchao Men, Jian Chen, Yining Liu, Jinxuan He, Bing Geng.  (2019)  Fluoropolymer/SiO2 encapsulated aluminum pigments for enhanced corrosion protection.  APPLIED SURFACE SCIENCE,  487  (1000). 
14. Umair Azhar, Rimsha Yaqub, Huateng Li, Ghulam Abbas, Yongkang Wang, Jian Chen, Chuanyong Zong, Anhou Xu, Zhang Yabin, Shuxiang Zhang, Bing Geng.  (2020)  Di-block copolymer stabilized methyl methacrylate based polyHIPEs: Influence of hydrophilic and hydrophobic co-monomers on morphology, wettability and thermal properties.  Arabian Journal of Chemistry,  13  (3801). 
15. Jiayan Shi, Yifei Zhou, Jiapei Jiang, Tingting Pan, Zhipeng Mei, Jiaxing Wen, Cheng Yang, Zijin Wang, Yanqing Tian.  (2019)  Multi-arm polymers prepared by atom transfer radical polymerization (ATRP) and their electrospun films as oxygen sensors and pressure sensitive paints.  EUROPEAN POLYMER JOURNAL,  112  (214). 
16. Jiaze Li, Yuan Qiao, Tingting Pan, Ke Zhong, Jiaxing Wen, Shanshan Wu, Fengyu Su, Yanqing Tian.  (2018)  Amphiphilic Fluorine-Containing Block Copolymers as Carriers for Hydrophobic PtTFPP for Dissolved Oxygen Sensing, Cell Respiration Monitoring and In Vivo Hypoxia Imaging with High Quantum Efficiency and Long Lifetime.  SENSORS,  18  (11): (3752). 
17. Umair Azhar, Chuanyong Zong, Xiaozheng Wan, Anhou Xu, Zhang Yabin, Jitao Liu, Shuxiang Zhang, Bing Geng.  (2018)  Methyl Methacrylate HIPE Solely Stabilized by Fluorinated Di-block Copolymer for Fabrication of Highly Porous and Interconnected Polymer Monoliths.  CHEMISTRY-A EUROPEAN JOURNAL,  24  (45): (11619-11626). 
18. Shi Wang, Hao Xu, Ailian Wang, Xu Liu, Jie Chen, Zhinan Wang, Di Feng, Qinghui Zeng, Liaoyun Zhang.  (2018)  Nanocomposite All-Solid-State Polymer Electrolyte for High-Performance Lithium Batteries.  Energy Technology,  (1): (122-130). 
19. Umair Azhar, Chenxi Huyan, Xiaozheng Wan, Anhou Xu, Hui Li, Bing Geng, Shuxiang Zhang.  (2017)  A cationic fluorosurfactant for fabrication of high-performance fluoropolymer foams with controllable morphology.  MATERIALS & DESIGN,  124  (194). 
20. Cheng Fang, Yi Jing, Yajun Zong, Zhongxiang Lin.  (2016)  Preparation and characterization of fluorine-containing acrylic latex PSAs using a reactive surfactant.  JOURNAL OF FLUORINE CHEMISTRY,  192  (113). 
21. Haochuan Chen, Changwen Zhao, Ruibo Li, Yuhong Ma, Lianying Liu, Wantai Yang.  (2014)  A Facile Visible-Light-Induced Route to Functionalize Polymeric Substrates by Combining Controlled Radical Grafting Polymerization and Thiol−Yne Click Chemistry with Photoredox Catalyst Ir(ppy)3.  MACROMOLECULAR CHEMISTRY AND PHYSICS,  215  (14): (1378-1387). 
22. Pengwei Jin, Ju Chu, Yu Miao, Jun Tan, Siliang Zhang, Weihong Zhu.  (2013)  A NIR luminescent copolymer based on platinum porphyrin as high permeable dissolved oxygen sensor for microbioreactors.  AICHE JOURNAL,  59  (8): (2743-2752). 
23. Shengyang Pan,Min Chen,Limin Wu.  (2018-03-27)  Synthesis of raspberry-like polymer/SiO2 hybrid colloidal spheres grafted by block-copolymer poly(MPC-b-MPS) for underwater superoleophobic anti-biofouling coatings..  Journal of colloid and interface science,  522  (20-28). 
24. Jianling Tian, Ruiyang Li, Xueying Yang, Pengbin Lai, Jiaxiang Liu, Ruilai Ye, Yi Deng, Qichen Chen, Peng Zhang, Jinbao Zhao.  (2024)  A fluorinated branched polyether for PEO-based polymer electrolyte via thiol-Michael addition click reaction.  SOLID STATE IONICS,  412  (116602). 
25. Cong Ma, Zuowei Zhang, Yihai Yang, Peixiang Wang, Meina Yu, Yanzi Gao, Qian Wang, Jiumei Xiao, Cheng Zou, Huai Yang.  (2024)  A Smart Window with Passive Radiative Cooling and Switchable Near-Infrared Light Transmittance via Molecular Engineering.  ACS Applied Materials & Interfaces,  16  (19): (25343-25352). 
26. Zhongqiang Yu, Wen Sun, Lida Wang, Zhengqing Yang, Yine Ren, Yanke Li, Guichang Liu, Qian Zhang.  (2024)  Bioinspired Sulfobetaine Borneol Fluorinated Amphiphilic Polymers for Marine Antifouling and Fouling Release Applications.  ACS Applied Materials & Interfaces,  16  (35): (46690-46702). 
27. Honghe Song, Yuheng Jiang, Caixiang Chen, Shumei Wen, Zhenzhen Zhou, Chenghu Yan, Wei Cong.  (2024)  Durable photobioreactor antibiofouling coatings for microalgae cultivation by photoreactive poly(2,2,2-trifluoroethyl methacrylate).  BIOFOULING,     
28. Yeyun Meng, Shengyuan Liang.  (2024)  Preparation and characterization of hydrophobic waterborne polyurethane self-matting coating.  JOURNAL OF APPLIED POLYMER SCIENCE,  141  (31): (e55734). 
29. Chengmin Hou, Weimin Yan, Na Li, Jiaqi Song, Qianqian Liao, Kexin Li, Qianruo Chen, Qi Gui.  (2024)  Preparation and properties of hydrophobic materials based on environmentally responsive low fluorine epoxy copolymer.  Journal of Environmental Chemical Engineering,  12  (111927). 
30. Xiangyu Xu, Yuxuan Fu, Zhongren Shi, Chao Li, Yan Kuai, Zhijia Hu, Zhigang Cao, Siqi Li.  (2024)  Stable and self-healing perovskite for high-speed underwater optical wireless communication.  Journal of Materials Chemistry C,  12  (11): (3907-3914). 
31. Yuting Tian, Weining Liu, Jun Hu, Zhiwei Li, Xiaoying Xin, Guodong Fu.  (2024)  Synthesis of highly transparent and fast-responding photochromic coating by template method with space-limited domains.  CHEMICAL ENGINEERING JOURNAL,  500  (156961). 
32. Wenbo Du, Zhiyong Lin, Ting Chen, Yongming Chen, Weiang Luo, Birong Zeng, Guorong Chen, Lizong Dai.  (2024)  Synthesis of phosphorus fluorine containing polymers for flame-retardant, low surface energy and good dielectric performance epoxy resin electronic packaging materials.  POLYMER DEGRADATION AND STABILITY,  229  (110932). 

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