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[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium - Pd 14.5%, high purity , CAS No.72287-26-4

    Grade & Purity:
  • Pd 14.5%
In stock
Item Number
D107566
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D107566-250mg
250mg
3
$19.90
D107566-1g
1g
2
$49.90
D107566-5g
5g
2
$199.90
D107566-10g
10g
Available within 8-12 weeks(?)
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$309.90
D107566-25g
25g
Available within 4-8 weeks(?)
Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!
$599.90
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Catalyzer (100)

Basic Description

Synonyms Umicore CX93 | Pd(dppf)Cl2
Specifications & Purity Pd 14.5%
Storage Temp Argon charged
Shipped In Normal
Product Description

A catalyst for Suzuki and Stille couplings

Catalyst for C-C and C-N coupling reaction.

Pd(dppf)Cl2 may be used as an effective palladium catalyst in the following reactions:

· Cross-coupling of sec-alkyl and n-alkyl Grignard reagents with high yield and selectivity. 

· Suzuki coupling of aryl boronic esters with [11C]methyl iodide to form functionalized [11C]toluene derivatives. 

· Kumada cross-coupling of 1,3,5-tribromobenzene with Grignard reagents to form star-shaped oligothiophenes.


Product class

M-P, Homogeneous Catalysts, Bidentate Ligands, Ferrocenyl Ligands - Achiral


Reaction type

Cross Coupling Reactions with Arenes, Amination, Buchwald-Hartwig Aminaton, C-H Activation, Carbonylation, Negishi Coupling Reaction, Stille Reaction, Suzuki-Miyaura Coupling Reaction, Oxidation


Chemical properties

Chemical formula

C34H28Cl2FeP2Pd

Empirical formula

[Pd(dppf)Cl2]

Molecular weight

731.71

Metal

Pd

Theoretical metal content

14

Physical state

crystalline

Color

red


Applications & references

Reductive carbonylation of aryl halides as an alternative and mild route for the introduction of aldehyde functionality, which is mostly desired for fine chemical and pharmaceutical intermediates to open up the wide range of further possible transformations.


Reference: Org. Proc. Res. Dev. 2007, 11, 39. (DOI: 10.1021/op060193w), Synthesis 1996, 470 (DOI: 10.1055/s-1996-4246)


High yielding Palladium catalyzed C-H arylation of electron-enriched heteroarenes with aryl bromides.


Reference: J. Org. Chem. 2010, 75, 6998. (DOI: 10.1021/jo101433g)

Names and Identifiers

WGK Germany 3
Molecular Weight 731.7

Certificates(CoA,COO,BSE/TSE and Analysis Chart)

C of A & Other Certificates(BSE/TSE, COO):
Analytical Chart:

Find and download the COA for your product by matching the lot number on the packaging.

17 results found

Lot Number Certificate Type Date Item
G2320204 Certificate of Analysis Jun 17, 2025 D107566
F2527363 Certificate of Analysis Jun 10, 2025 D107566
F2527364 Certificate of Analysis Jun 10, 2025 D107566
F2527365 Certificate of Analysis Jun 10, 2025 D107566
F2527366 Certificate of Analysis Jun 10, 2025 D107566
F2527367 Certificate of Analysis Jun 10, 2025 D107566
D2514065 Certificate of Analysis Apr 21, 2025 D107566
E2430013 Certificate of Analysis Jun 03, 2024 D107566
G2222234 Certificate of Analysis Apr 07, 2024 D107566
G2222231 Certificate of Analysis Apr 07, 2024 D107566
L2102005 Certificate of Analysis Sep 18, 2023 D107566
L2101316 Certificate of Analysis Sep 18, 2023 D107566
I2010044 Certificate of Analysis Jul 14, 2022 D107566
I2010043 Certificate of Analysis Jul 14, 2022 D107566
G2222233 Certificate of Analysis Jun 04, 2022 D107566
C2415107 Certificate of Analysis Jun 04, 2022 D107566
A2431229 Certificate of Analysis Jun 04, 2022 D107566

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Chemical and Physical Properties

Solubility Soluble in dichloromethane.
Sensitivity Air & Moisture sensitive.
Melt Point(°C) 275-280°C

Citations of This Product

1. Fei Zhang, Zhe Li, Yaoming Liu, Binsheng Yang, Hui Qiao, Jie Chai, Guangming Wen, Bin Liu.  (2020)  Rational construction of AIEgens with wide color tunability and their specific lipid droplet imaging applications.  Journal of Materials Chemistry B,  (41): (9533-9543). 
2. Fei Zhang, Yaoming Liu, Binsheng Yang, Guangming Wen, Bin Liu.  (2020)  Near-infrared AIEgens for lipid droplets imaging in corpus adiposum or trachea of Locusta migratoria and its application in photodynamic therapy.  SENSORS AND ACTUATORS B-CHEMICAL,  322  (128589). 
3. Zhiyuan Zeng, Tianqun Zhao, Yi Gong, Zhiqiang Yu.  (2024)  Synthesis, curing kinetics and properties of novel aromatic multifunctional epoxy resin.  EUROPEAN POLYMER JOURNAL,  219  (113375). 

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